A team of researchers from the National University of Singapore (NUS) have made a serendipitous scientific discovery that could potentially revolutionise the way water is broken down to release hydrogen gas - an element crucial to many industrial processes.
The team, led by Associate Professor Xue Jun Min, Dr Wang Xiaopeng and Dr Vincent Lee Wee Siang from the Department of Materials Science and Engineering under the NUS College of Design and Engineering (NUS CDE), found that light can trigger a new mechanism in a catalytic material used extensively in water electrolysis, where water is broken down into hydrogen and oxygen. The result is a more energy-efficient method of obtaining hydrogen.
This breakthrough was achieved in collaboration with Dr Xi Shibo from the Institute of Sustainability for Chemicals, Energy and Environment under the Agency for Science, Technology and Research (A*STAR); Dr Yu Zhigen from the Institute of High Performance Computing under A*STAR; and Dr Wang Hao from the Department of Mechanical Engineering under the NUS CDE.
“We discovered that the redox center for electro-catalytic reaction is switched between metal and oxygen, triggered by light,” said Assoc Prof Xue. “This largely improves the water electrolysis efficiency.”
The new finding can potentially open up new and more effective industrial methods of producing hydrogen and putting this environmentally friendly source of fuel within the reach of more people and industries.
Assoc Prof Xue and his team detailed their discovery in a research paper published in renowned scientific journal Nature on 26 October 2022.
The groundbreaking discovery made by Assoc Prof Xue Jun Min (centre) and his team could improve affordability of hydrogen as source of clean energy.
The accidental breakthrough
Under normal circumstances, Assoc Prof Xue and his team may not have been able to come across such a groundbreaking discovery. But an accidental power trip of the ceiling lights in his laboratory almost three years ago allowed them to observe something that the global scientific community has not yet managed to do.
Back then, the ceiling lights in Assoc Prof Xue’s research lab were usually turned on for 24 hours. One night in 2019, the lights went off due to a power trip. When the researchers returned the next day, they found that the performance of a nickel oxyhydroxide-based material in the water electrolysis experiment, which had continued in the dark, had fallen drastically.
“This drop in performance, nobody has ever noticed it before, because no one has ever done the experiment in the dark,” said Assoc Prof Xue. “Also, the literature says that such a material shouldn’t be sensitive to light; light should not have any effect on its properties.”
The electro-catalytic mechanism in water electrolysis is a very well-researched topic, while the nickel-based material is a very common catalytic material. Hence, in order to establish that they were on the verge of discovering something groundbreaking, Assoc Prof Xue and his team embarked on numerous repeated experiments. They dug deeper into the mechanics behind such a phenomenon. They even repeated the experiment outside of Singapore to ensure that their findings were consistent.
Three years on, Assoc Prof Xue and his team were finally able to share their findings publicly in a paper.
